para-nitrophenol has more boiling point than the ortho-nitrophenol.Why ?
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It happen because para nitrophenol better fit in the crystal lattice has hence it has high boiling point.
SharmaAnil:
No it is due to the intermolecular hydrogen bonding in para-nitrophenol whereas in case of ortho-nitrophenol there is intramolecular hydrogen bonding that's why .
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