penetration effect or orbital effect
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Explanation:
Penetration effect is the effect in which ionization enthalpy is increased through this effect. ✔As we know , The electrons of the S orbital has the maximum probability of being found near the Nucleus. AND , LESS probability in case of P , D , and F orbitals in the same shells.
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Penetration describes the proximity of electrons in an orbital to the nucleus. Electrons which experience greater penetration experience less shielding and therefore experience a larger Effective Nuclear Charge (Zeff), but shield other electrons more effectively.
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