photochemical chlorination of alkane is initiated by aprocess of (1) hemolysis (2) pyrolysis (3) substitution (4) hetrolysis
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Photochemical chlorination of alkane takes place by free radical mechanism which are possible by homolysis of Cl−Cl bond by sunlight.
Cl
2
hν
Cl
∙
+Cl
∙
CH
3
−CH
3
+Cl
∙
⟶
∙
CH
2
CH
3
+HCl
Cl−Cl+
∙
CH
2
CH
3
⟶Cl−CH
2
CH
3
+Cl
∙
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photochemical chlorination of alkane is initiated by aprocess of pyrolysis
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