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Boyle’s Law
Boyle’s law states the relation between volume and pressure at constant temperature and mass. Robert Boyle conducted an experiment on gases to study the deviation of its behaviour in changed physical conditions.
It states that under a constant temperature when the pressure on a gas increases its volume decreases. In other words according to Boyle’s law volume is inversely proportional to pressure when the temperature and the number of molecules are constant.
p ∝ 1/V
p = k1 1/V
Charle’s Law
Jacques Charles in 1787 analyzed the effect of temperature on the volume of a gaseous substance at a constant pressure. He did this analysis to understand the technology behind the hot air balloon flight. According to his findings, at constant pressure and for constant mass, the volume of a gas is directly proportional to the temperature.
Gay-Lussac’s law
Also referred to as Pressure-Temperature Law, Gay Lussac’s Law was discovered in 1802 by a French scientist Joseph Louis Gay Lussac. While building an air thermometer, Gay-Lussac accidentally discovered that at fixed volume and mass of a gas, the pressure of that gas is directly proportional to the temperature. This mathematically can be written as: p ∝ T
⇒ p/T = constant= k3
The temperature here is measured on the Kelvin scale. The graph for the Gay- Lussac’s Law is called as an isochore because the volume here is constant
Avogadro’s Law
Amedeo Avogadro in 1811 combined the conclusions of Dalton’s Atomic Theory and Gay Lussac’s Law to give another important Gas law called the Avogadro’s Law. According to Avogadro’s law, at constant temperature and pressure, the volume of all gases constitutes an equal number of molecules. In other words, this implies that in unchanged conditions of temperature and pressure the volume of any gas is directly proportional to the number of molecules of that gas.
Mathematically, V ∝ n
Here, n is the number of moles of the gas. Hence, V= k4n