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Hi!
The correct answer for that question is option 4
Explanation:
According to Raoult's law in general form(solid in liquid solutions), for any solution, the partial pressure of each volatile component in the solution is directly proportional to its mole fraction.
There is a graph given in NCERT (Part 1) regarding this on page 47.
I will attach a photo along with this answer. I hope you will be able to recognise it as the option 4 of the question. All the other graphs are for liquid liquid solutions.
I hope you find it helpful.
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