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Explanation:
Mass percent of HNO3 in sample is 69 %
Thus, 100 g of HNO3 contains 69 g of HNO3 by mass.
Molar mass of HNO3
= { 1 + 14 + 3(16)} g.mol^{-1}g.mol
−1
= 1 + 14 + 48
= 63g\;mol^{-1}=63gmol
−1
Now, No. of moles in 69 g of HNO_{3}HNO
3
:
= \frac{69\:g}{63\:g\:mol^{-1}}
63gmol
−1
69g
= 1.095 mol
Volume of 100g HNO3 solution
= \frac{Mass\;of\;solution}{density\;of\;solution}
densityofsolution
Massofsolution
= \frac{100g}{1.41g\;mL^{-1}}
1.41gmL
−1
100g
= 70.92mL
= 70.92\times 10^{-3}\;L70.92×10
−3
L
Concentration of HNO3
= \frac{1.095\:mole}{70.92\times 10^{-3}L}
70.92×10
−3
L
1.095mole
= 15.44mol/L
Therefore, Concentration of HNO3 = 15.44 mol/L
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