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Ligands, such as NCS-, that can bond to a central atom through either of two or more donor atoms are termed ambidentate.
Another example of an ambidentateligans is thiocyanate, SCN−, which can attach at either the sulfur atom or the nitrogen atom. Such compounds give rise to linkage isomerism. Polyfunctional ligands can bond to a metal center through different ligandatoms to form various isomers.
Another example of an ambidentateligans is thiocyanate, SCN−, which can attach at either the sulfur atom or the nitrogen atom. Such compounds give rise to linkage isomerism. Polyfunctional ligands can bond to a metal center through different ligandatoms to form various isomers.
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