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potato chip bags are not full of air, but of nitrogen gas. this is done to prevent the chips from oxidizing, which is part of What makes them go stale. oxygen is very reactive, and likes to combine with other molecules whenever it can, causing chemical changes to take place.
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The bag used for potato chips is flushed with nitrogen gas to prevent the contact of oxygen present in the atmosphere. This is done to prevent rancidity of fats and oil.
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