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First is that nitrogen is less likely to migrate through tire rubber than is oxygen, which means that your tire pressures will remain more stable over the long term. Racers figured out pretty quickly that tires filled with nitrogen rather than air also exhibit less pressure change with temperature swings.
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Air is a gaseous substance. The intermolecular between the particles in the gaseous form is negligible. Thus, the distance between the molecules of air is very high. Air being gaseous is compressible. Thus, by applying pressure the molecule of air can be forced to get closer. so they can be compressed. Thus,air can be filled in more proportion in tyres.
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