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1. Toleune undergoes nitration most easily due to electrons releasing nature of the methyl group. Solution : The ease of nitration depends on the presence of electron density on the compound to form nitrates
2.As branching increases, the surface area of the molecule decreases which results in a small area of contact. As a result, the Van der Waals force also decreases which can be overcome at a relatively lower temperature. Hence, the boiling point of an alkane chain decreases with an increase in branching
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