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Class 12th chemistry.
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let the pressure of N2O5 decease by 2x atm.
As two Mole of O2 decompose to give two moles of N2O4 ,and one Mole of O2 , the pressure of N2O5 increases by 2x atm and that of O2 increase by x atm..
pt = pN2O5 +pN2O4+pO2
=(0.5-2X)+2X+X=0.5
X=pt-0.5
pN2O5=0.5-2X=0.5-2(pt-0.5)=1.5-2pt
=(0.5-2x)+2x+x=0.5+x
x=pt-0.5
pN2O5=0.5-2X=0.5-2(pt-0.5)=1.5-2pt
At,t=100s;pt=0.512atm
pN2O5=1.5-2×0.512=0.476at.
Thus,k=2.303/t log pi/pa
2.303/100s log 0.5atm/0.476atm
2.303/100s×0.0216=4.98×10^-4 s^-1
I hope it was helpful.....thank u
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