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13 a) in KMnO4 usual oxid. satate of O is -2 and for K it is +1
hence oxidation state of Mn be x= x-2(4)+1=0
x=+7
hence oxid of Mn=+7
similarly in H2S2O7
usual oxid state of H=+1,O=-2
hence 2x-2(7)+1(2)=0
2x=12
x=+6
oxid state of s=+6
in H3PO3
x+1(3)-2(3)=0
x=+3
oxid state of P=+3
part (b)
value of emf can be calculated=emf at reduction-emf at oxidation
emf=-0.25-(-0.76)
emf of cell=0.51 volts
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