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Obtain the dimensions of a and b in the given equation :
(P+ a/V^2)(v - b) = nRT
where, P is pressure and V is volume.
Note;
Principle of homogeneity;
It states that , in a correct physical expression all the terms must have same dimensions.In other words, only the similar quantities can be added or subtracted.
Solution;
According to the principle of homogeneity, we have;
=> [b] = [volume]
=> [b] = [L^3]
Also;
=> [a/V^2] = [pressure]
=> [a/(L^3)^2] = [M L^(-1) T^(-2)]
=> [a]/[L^6] = [M L^(-1) T^(-2)]
=> [a] = [M L^(-1) T^(-2) L^6]
=> [a] = [M L^5 T^(-2)]
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