Polyhedral description of solids-structure of na2o
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Explanation:
Coordination – Na+ 4 (tetrahedral) : O2- 8 (cubic)
ccp O2- with Na+ in all Td holes
Polyhedra – Edge-sharing NaO4 tetrahedra, edge-sharing ONa8 cubes
Anions form the cubic close packing
while cations fill all tetrahedral holes.
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so far the NaCl, ZnS and Na2O structure have been described in two ... consider how neighboring polyhedra are linked in 3D. ... Two distinct descriptions in a 3D network
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