Potassium crystallize in a bcc lattice with density 0.856g per cm3. Calculate the radius of k atom and the edge length of cell.
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Solution:
1) Convert pm to cm:
330.6 pm x 1 cm/1010 pm = 330.6 x 10¯10 cm = 3.306 x 10¯8 cm
2) Calculate the volume of the unit cell:
(3.306 x 10¯8 cm)3 = 3.6133 x 10¯23 cm3
3) Calculate mass of the 2 tantalum atoms in the body-centered cubic unit cell:
16.69 g/cm3 times 3.6133 x 10¯23 cm3 = 6.0307 x 10¯22 g
4) The mass of one atom of Ta:
6.0307 x 10¯22 g / 2 = 3.015 x 10¯22 g
5) The atomic weight of Ta in g/mol:
3.015 x 10¯22 g times 6.022 x 1023 mol¯1 = 181.6 g/mol
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