primary amines have higher boiling point than tertiary .why
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In a tertiary amine there aren't any hydrogen atoms attached directly to the nitrogen. That means that hydrogen bonding between tertiary amine molecules is impossible. ... Therefore primary amines have higher boiling point than tertiary amines.
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Explanation: It's because primary amines have more no of hydrogen when compared to tertiary amines so the extent of hydrogen bonding is more in Primary amines thus the boiling point of them is more than that of tertiary amines
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