Chemistry, asked by kanhaiya3894, 1 year ago

Process involved in carbylamine reaction

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Answered by Anonymous
1
hii dear!!

here ur answer!!

▪Carbylamine reaction is a reaction to detect primary amine and chloroform. This test is also used to distinguish primary amine from secondary and tertiary amines. According to the mechanism, this is one of the best examples of Alpha elimination reaction,in which carbanion is formed in very first step which latter loses chloride Ion to form highly reactive dichlorocarbene. Now remaining two chlorine atoms get removed in the form of HCL. For that hydrogen is provided from the nitrogen in amine.


▪In secondary and tertiary amines nitrogen do not have that much hydrogen atoms ,and also sterically highly unstable product would be expected, if secondary and tertiary amine wood reacted. And very important thing alkyl isocyanides are unpleasant smelling compounds .Hence we use this test to detect primary amines only...


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