Prove that the enthalpy of the humid air remains constant along a wet bulb temperature
line on the psychrometric chart.
Answers
In order to perform air conditioning calculations, it is essential first to estimate
various properties of air. It is difficult to estimate the exact property values of moist
air as it is a mixture of several permanent gases and water vapour. However, moist
air upto 3 atm. pressure is found to obey perfect gas law with accuracy sufficient for
engineering calculations. For higher accuracy Goff and Gratch tables can be used
for estimating moist air properties. These tables are obtained using mixture models
based on fundamental principles of statistical mechanics that take into account the
real gas behaviour of dry air and water vapour. However, these tables are valid for a
barometric pressure of 1 atm. only. Even though the calculation procedure is quite
complex, using the mixture models it is possible to estimate moist air properties at ther pressures also. However, since in most cases the pressures involved are low,
one can apply the perfect gas model to estimate psychrometric properties