prove that the half life period for a first order reaction does not depend on the initial concentration of reactant.
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Plot the rotational partition function of N_22 as a function of temperature from 10 to 300 K. At what temperature (in K) does the approximation of q_r=\frac{T}{\Theta_r}qr=ΘrT (Eq. 5.49) result in less than 1% error?
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