pure rotational spectrum of diatomic molecule, the spacing distance is equal to ?
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For a rigid rotor diatomic molecule, the selection rules for rotational transitions are ΔJ = +/-1, ΔMJ = 0 . The rotational spectrum of a diatomic molecule consists of a series of equally spaced absorption lines, typically in the microwave region of the electromagnetic spectrum.
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In the pure rotational spectrum of a diatomic molecule, the spacing distance is equal to 2B.
- For the pure rotational spectrum of a diatomic rigid molecule, the spacing between various energy levels is 2B.
- Here B is called rotational constant.
- The value of B is given as-
- .
- Where h is the plank's constant.
- 'I' is the moment of inertia.
- Here 'c' is the speed of light.
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