Q.11. Expain nucleophilic substitution in p-nitrochlorobenzene on the basis of resonan stabilization of the intermediate.
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In p-nitrochlorobenzenzene a carbanion intermediate is formed. This is stabilised by resonance as shown below.
The-I effect of nitrogen group furthure stabilises the intermediate. Hence, p-nitrochlorobenzene reacts faster than chlorobenzene.
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In p-nitrochlorobenzene a carbanion intermediate is formed. This is stabilized by resonance as shown below.
The-I effect of the nitrogen group further stabilizes the intermediate. Hence, p-nitrochlorobenzene reacts faster than chlorobenzene.
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