Q.17Balance the following redox reaction by any method showing all the steps:
Cr₂O7² m + Fe (aut
→Cri
(aq)
+ Pen
cap (Acidic medium)
MnO, +
and
MnO2 + 1; (Basic medium)
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Answered by
1
Explanation:
Answer
(i) K2Cr2O7+KI+H2SO4→K2SO4+Cr2(SO4)3+I2+H2O
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Equate increase and decrease of oxidation number
K2Cr2O7+6KI+H2SO4→K2SO4+Cr2(SO4)3+3I2+H2O
Equate number of potassium and then SO42− and then hydropen
K2Cr2O7+6KI+7H2SO4→4K2SO4+Cr2
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Answered by
2
Explanation:
The oxidation half reaction is SO2(g)+2H2O(l)→SO42−+4H+(aq)+2e−.
The reduction half reaction is Cr2O72−(aq)+14H+(aq)+6e−→2Cr3+(aq)+7H2O(l).
The oxidation half reaction is multiplied by 3 and added to the reduction half reaction to obtain the balanced redox reaction.
Cr2O72−+3SO2(g)+2H+(aq)→2Cr3+(aq)+3SO42−(aq)+H2O(l)
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