Q coloumbs of charge deposits 'X'g of Mg. Now,
to deposit same quantity of Ag, charge required
in coloumbs is
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Given info : Q Coulombs of charge deposits X g of Mg.
To find : to deposit same amount of Ag, charge required in Coulombs is .....
Solution : half reduction reaction of Mg is ...
Mg²⁺ + 2e¯ ⇒Mg
here it is clear that, 2 mole of electron is required to deposit 1 mole of Mg.
so, 2mole of electron deposits 24 g of Mg
⇒2/24 × X mole of electron deposits X g of Mg.
i.e., Q = X/12 mole of electron .....(1)
Now half reduction reaction of Ag,
Ag⁺ + e¯⇒Ag
i.e., 1 mole of electron deposits 1 mole of Ag.
⇒1/108 × x mole of electron deposits x g of Ag.
charge = x/108 = x/(12 × 9) = (x/12) × 1/9
from eq (1).
Charge = Q/9
Therefore charge required to deposit X g of Ag is Q/9.
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