Q.. Ortho and para nitrophenols are more acidic than phenol. Draw the resonance structures of the corresponding phenoxide ions.
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The electron withdrawing groups are more effective in increasing the acidic strength at the para-position relative to the ortho position because of greater dispersal of charge on oxygen atom. Resonance structure of phenoxide ion: ... Thus, presence of nitro group at ortho and para position incerease the acidic character
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