Q1. How will you distinguish between aniline and benzylamine?
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Aniline and benzylamine can be distinguished by their reactions with the help of nitrous acid, which is prepared from a mineral acid and sodium nitrite. Benzylamine reacts with nitrous acid to form unstable diazonium salt, which in turn gives alcohol with the evolution of nitrogen gas.
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ᴀɴɪʟɪɴᴇ ᴀɴᴅ ʙᴇɴᴢʏʟᴀᴍɪɴᴇ ᴄᴀɴ ʙᴇ ᴅɪꜱᴛɪɴɢᴜɪꜱʜᴇᴅ ʙʏ ᴛʜᴇɪʀ ʀᴇᴀᴄᴛɪᴏɴꜱ ᴡɪᴛʜ ᴛʜᴇ ʜᴇʟᴘ ᴏꜰ ɴɪᴛʀᴏᴜꜱ ᴀᴄɪᴅ, ᴡʜɪᴄʜ ɪꜱ ᴘʀᴇᴘᴀʀᴇᴅ ꜰʀᴏᴍ ᴀ ᴍɪɴᴇʀᴀʟ ᴀᴄɪᴅ ᴀɴᴅ ꜱᴏᴅɪᴜᴍ ɴɪᴛʀɪᴛᴇ. ʙᴇɴᴢʏʟᴀᴍɪɴᴇ ʀᴇᴀᴄᴛꜱ ᴡɪᴛʜ ɴɪᴛʀᴏᴜꜱ ᴀᴄɪᴅ ᴛᴏ ꜰᴏʀᴍ ᴜɴꜱᴛᴀʙʟᴇ ᴅɪᴀᴢᴏɴɪᴜᴍ ꜱᴀʟᴛ, ᴡʜɪᴄʜ ɪɴ ᴛᴜʀɴ ɢɪᴠᴇꜱ ᴀʟᴄᴏʜᴏʟ ᴡɪᴛʜ ᴛʜᴇ ᴇᴠᴏʟᴜᴛɪᴏɴ ᴏꜰ ɴɪᴛʀᴏɢᴇɴ ɢᴀꜱ.
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