Q63 For which of the following molecule observed bond length is less longer than theoretically determined bond length ?
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PCl
5
has trigonal bipyramidal structure in which bond angles of 90
∘
and 120
∘
exist. Hence, two types of bond length are observed, axial bonds are longer than the equatorial bonds while in case of SF
6
, there is only one type of angle (90
∘
) and has octahedral structure.
Therefore, the statement is correct.
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