QII.
The boiling point of a solution of urea in water is 100.13° C. Calculate freezing point of
solution. (Kf=1.86 K kg mol!, Ky=0.52 kkg mol ).
(molar mass of urea = 60 g mol').
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ΔTf =kf m ( 1)
ΔTb =Kb m. ( 2)
100.13-100/Tf = 0.52 /1.86
0.13 X 1.86/0.52 =Tf = -0.465
.
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