Question 12.13 Identify the reagents shown in bold in the following equations as nucleophiles or electrophiles:
Class XI Organic Chemistry : Some Basic Principles and Techniques Page 362
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Electrophile :- ELECTRO + PHILLIC
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electron loving
(-ve charge)
electrophile means negative center loving species.
the species that can accept an electron pair is known as electrophile.
How to identified a electrophile:
1. all simple cation is electrophile ( H⁺,Br⁺,NO⁺ etc)
2. The species with vacant d- orbital in central atom (PCl₃,SF₆
3. All halogens
4. atoms with sextet (O,S, Se etc)
(b)NUCLEOPHILE : NUCLEO + PHILE
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nucleus loving
(+ve charge)
thus, positive center loving species are known as nucleophile.
the species that can give a lone pair of electron is known as nucleophile.
How to identified nucleophile :
1. usually anions are nucleophile (NH₂⁻,OH⁻,CH₃⁻ etc)
2. the species having lone pair on the central atom are nucleophiles.(NH₃,H₂O,ROH etc)
after learning about nucleophile and electrophile . now solve the question.
(a) OH⁻ is electron-rich species hence it acts as nucleophile.
(b) CN⁻ is electron-rich species hence, it acts as nucleophile.
(c) CH₃CO⁺ is electron-deficient species, it acts as electrophile.
| |
electron loving
(-ve charge)
electrophile means negative center loving species.
the species that can accept an electron pair is known as electrophile.
How to identified a electrophile:
1. all simple cation is electrophile ( H⁺,Br⁺,NO⁺ etc)
2. The species with vacant d- orbital in central atom (PCl₃,SF₆
3. All halogens
4. atoms with sextet (O,S, Se etc)
(b)NUCLEOPHILE : NUCLEO + PHILE
| |
nucleus loving
(+ve charge)
thus, positive center loving species are known as nucleophile.
the species that can give a lone pair of electron is known as nucleophile.
How to identified nucleophile :
1. usually anions are nucleophile (NH₂⁻,OH⁻,CH₃⁻ etc)
2. the species having lone pair on the central atom are nucleophiles.(NH₃,H₂O,ROH etc)
after learning about nucleophile and electrophile . now solve the question.
(a) OH⁻ is electron-rich species hence it acts as nucleophile.
(b) CN⁻ is electron-rich species hence, it acts as nucleophile.
(c) CH₃CO⁺ is electron-deficient species, it acts as electrophile.
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