Chemistry, asked by Rajput2stars, 10 months ago

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2ᵍ ᵒᶠ ᵇᵉⁿᶻᵒⁱᶜ ᵃᶜⁱᵈ (ᶜ6ʰ5ᶜᵒᵒʰ) ᵈⁱˢˢᵒˡᵛᵉᵈ ⁱⁿ 25ᵍ ᵒᶠ ᵇᵉⁿᶻᵉⁿᵉ ˢʰᵒʷˢ ᵃ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ⁱⁿ ᶠʳᵉᵉᶻⁱⁿᵍ ᵖᵒⁱⁿᵗ ᵉQ꙰ᵘᵃˡ ᵗᵒ 1.62 ᵏ. ᵐᵒˡᵃʳ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ᶜᵒⁿˢᵗᵃⁿᵗ ᶠᵒʳ ᵇᵉⁿᶻᵉⁿᵉ ⁱˢ 4.9 ᵏ ᵏᵍ/ᵐᵒˡ. ʷʰᵃᵗ ⁱˢ ᵗʰᵉ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ᵃˢˢᵒᶜⁱᵃᵗⁱᵒⁿ ᵒᶠ ᵃᶜⁱᵈ ⁱᵗ ⁱᶠ ᶠᵒʳᵐˢ ᵈⁱᵐᵉʳ ⁱⁿ ˢᵒˡᵘᵗⁱᵒⁿ?​

Answers

Answered by Anonymous
23

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2ᵍ ᵒᶠ ᵇᵉⁿᶻᵒⁱᶜ ᵃᶜⁱᵈ (ᶜ6ʰ5ᶜᵒᵒʰ) ᵈⁱˢˢᵒˡᵛᵉᵈ ⁱⁿ 25ᵍ ᵒᶠ ᵇᵉⁿᶻᵉⁿᵉ ˢʰᵒʷˢ ᵃ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ⁱⁿ ᶠʳᵉᵉᶻⁱⁿᵍ ᵖᵒⁱⁿᵗ ᵉQ꙰ᵘᵃˡ ᵗᵒ 1.62 ᵏ. ᵐᵒˡᵃʳ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ᶜᵒⁿˢᵗᵃⁿᵗ ᶠᵒʳ ᵇᵉⁿᶻᵉⁿᵉ ⁱˢ 4.9 ᵏ ᵏᵍ/ᵐᵒˡ. ʷʰᵃᵗ ⁱˢ ᵗʰᵉ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ᵃˢˢᵒᶜⁱᵃᵗⁱᵒⁿ ᵒᶠ ᵃᶜⁱᵈ ⁱᵗ ⁱᶠ ᶠᵒʳᵐˢ ᵈⁱᵐᵉʳ ⁱⁿ ˢᵒˡᵘᵗⁱᵒⁿ?

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Answered by aman7913
4

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▶given◀

W2 = 2 g

Kf = 4.9 K kg/mol

W1 = 25g

∆Tf = 1.62 K

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▶Solution◀

 m_{2} =  \frac{4.9k \: kg  \:  {mol}^{ - 1} \times 2g \times 1000g \:  {kg}^{ - 1}   }{25g \times 1.62k}  \\  = 241.98g \:  {mol}^{ - 1}

Thus, experimental molar mass of benzoic acid in benzene is

= 2.41.98g/mol

Now consider the following equilibrium for the acid:

2C6H6COOH -------> ( C6H5COOH)2

Thus, total number of molar of particles at equilibrium equals van't Hoff factor i.

i =  \frac{normal \: molar \: mass}{abnormal \: molar \: mass}  \\  \\  =  \frac{122g \:  {mol}^{ - 1} }{241.98g \:  {mol}^{ - 1} }  \\  \\  \frac{x}{2}  = 1 -  \frac{122}{241.98}  \\  \\  = 1 - 0.504 = 0.496 \\  \\ x = 2 \times 0.496 = 0.992

Therefore, degree of association of benzonic acid in benzene is 99.2.

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