|⭕+QUESTION+⭕|
2ᵍ ᵒᶠ ᵇᵉⁿᶻᵒⁱᶜ ᵃᶜⁱᵈ (ᶜ6ʰ5ᶜᵒᵒʰ) ᵈⁱˢˢᵒˡᵛᵉᵈ ⁱⁿ 25ᵍ ᵒᶠ ᵇᵉⁿᶻᵉⁿᵉ ˢʰᵒʷˢ ᵃ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ⁱⁿ ᶠʳᵉᵉᶻⁱⁿᵍ ᵖᵒⁱⁿᵗ ᵉQ꙰ᵘᵃˡ ᵗᵒ 1.62 ᵏ. ᵐᵒˡᵃʳ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ᶜᵒⁿˢᵗᵃⁿᵗ ᶠᵒʳ ᵇᵉⁿᶻᵉⁿᵉ ⁱˢ 4.9 ᵏ ᵏᵍ/ᵐᵒˡ. ʷʰᵃᵗ ⁱˢ ᵗʰᵉ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ᵃˢˢᵒᶜⁱᵃᵗⁱᵒⁿ ᵒᶠ ᵃᶜⁱᵈ ⁱᵗ ⁱᶠ ᶠᵒʳᵐˢ ᵈⁱᵐᵉʳ ⁱⁿ ˢᵒˡᵘᵗⁱᵒⁿ?
Answers
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2ᵍ ᵒᶠ ᵇᵉⁿᶻᵒⁱᶜ ᵃᶜⁱᵈ (ᶜ6ʰ5ᶜᵒᵒʰ) ᵈⁱˢˢᵒˡᵛᵉᵈ ⁱⁿ 25ᵍ ᵒᶠ ᵇᵉⁿᶻᵉⁿᵉ ˢʰᵒʷˢ ᵃ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ⁱⁿ ᶠʳᵉᵉᶻⁱⁿᵍ ᵖᵒⁱⁿᵗ ᵉQ꙰ᵘᵃˡ ᵗᵒ 1.62 ᵏ. ᵐᵒˡᵃʳ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ᶜᵒⁿˢᵗᵃⁿᵗ ᶠᵒʳ ᵇᵉⁿᶻᵉⁿᵉ ⁱˢ 4.9 ᵏ ᵏᵍ/ᵐᵒˡ. ʷʰᵃᵗ ⁱˢ ᵗʰᵉ ᵈᵉᵖʳᵉˢˢⁱᵒⁿ ᵃˢˢᵒᶜⁱᵃᵗⁱᵒⁿ ᵒᶠ ᵃᶜⁱᵈ ⁱᵗ ⁱᶠ ᶠᵒʳᵐˢ ᵈⁱᵐᵉʳ ⁱⁿ ˢᵒˡᵘᵗⁱᵒⁿ?
refer to the attachment!!
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▶given◀
W2 = 2 g
Kf = 4.9 K kg/mol
W1 = 25g
∆Tf = 1.62 K
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▶Solution◀
Thus, experimental molar mass of benzoic acid in benzene is
= 2.41.98g/mol
Now consider the following equilibrium for the acid:
2C6H6COOH -------> ( C6H5COOH)2
Thus, total number of molar of particles at equilibrium equals van't Hoff factor i.
Therefore, degree of association of benzonic acid in benzene is 99.2℅.
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