Chemistry, asked by sana123434, 1 year ago

ratio of wavelength of first line of Balmer series to first line of lyman series is

Answers

Answered by Anonymous
11
ur answer should be 27/5
do u need explaination ??

sana123434: thank you please answer my other chemistry questions also as my tests on Monday
Answered by kobenhavn
21

Answer:  Ratio of minimum wavelength of lyman and balmer series will be 27: 5.

Explanation:  

E=\frac{hc}{\lambda}

\lambda = Wavelength of radiation

E= energy

1. The wavelength of first line of balmer series i.e the electron will jump from n=2 to n=3.

Using Rydberg's Equation:

\frac{1}{\lambda}=R_H\left(\frac{1}{n_i^2}-\frac{1}{n_f^2} \right )

Where,

\lambda = Wavelength of radiation

R_H = Rydberg's Constant

n_f = Higher energy level = 3

n_i= Lower energy level = 2 (balmer series)

Putting the values, in above equation, we get

\frac{1}{\lambda_{lyman}}=R_H\left(\frac{1}{2^2}-\frac{1}{3^2} \right )

\lambda_{lyman}=\frac{5}{36R_H}

2. The wavelength of first line of lyman series i.e the electron will jump from n=1 to n=2

.\frac{1}{\lambda}=R_H\left(\frac{1}{n_i^2}-\frac{1}{n_f^2} \right )

Where,

\lambda = Wavelength of radiation

R_H = Rydberg's Constant

n_f = Higher energy level = 2

n_i= Lower energy level = 1 (Lyman series)

Putting the values, in above equation, we get

\frac{1}{\lambda_{balmer}}=R_H\left(\frac{1}{1^2}-\frac{1}{2^2} \right )

\lambda_{balmer}=\frac{3}{4R_H}

Thus \frac{\lambda_{balmer}}{\lambda_{lyman}}=\frac{\frac{3}{4R_H}}{\frac{5}{36R_H}}=\frac{27}{5}

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