Reaction of benzene chloride to bezenealcohal by koh
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C6H5-Cl ----KOH----->. C6H5-OH
-kCl
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Explanation:
In case of C6H5CH2Cl, the benzyl carbocation (C6H5C⊕H2) formed by releasing Cl− ion is resonance stabilised. Therefore, the C−Cl bond can cleave to form KCl. However, the phenyl carbocation (C6H⊕5) expected to be formed in case of chlorobenzene does not show any resonance. therefore, C−Cl bond does not cleave in case of chlorobenzene and no white precipitate is formed in this case.
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