reaction of cis 2-amino-cyclohexanol with HNO2
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The reaction of cis 2-amino-cyclohexanol with HNO2 will produce cyclohexanone.
Explanation:
- When cis-2-Aminocyclohexanol undergoes treatment with nitrous acid They undergo a pinacol rearrangement.
- They start yielding both cyclohexanone and cyclopentyl methanal as products.
- The pinacol rearrangement is a rearrangement for converting a 1,2-diol to a carbonyl compound.
- In organic chemistry it is very often used.
- Here the 1,2-rearrangement takes place under acidic conditions.
- This name of the rearrangement comes from the rearrangement that takes place from pinacol to pinacolone.
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