reaction of ketones with nitrous oxide
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Abstract
The reaction of ketone arylhydrazone (1) with nitric oxide affords C1′-nitro azo-compounds (2) in good yields. Products were identified by NMR, IR, MS, and X-ray crystallography. The reaction is assumed to be most likely initiated by an electrophilic addition of NO2 to the carbon atom of the carbonnitrogen double bond.
Reaction of nitric oxide with ketone arylhydrazones affords C1′-nitro azo-compounds.
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