Chemistry, asked by Anonymous, 5 months ago

Relation between Edge length and radius of particle in Body centred Unit cell

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Answered by Anonymous
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Answer:

For Body centered cubic cell with the relation between Edge length (a) and radius of particle (r).

AD=4r (since particles at body diagonal touch each other)

By Pythagoras' theorem

AC^{2} = AB^{2} +BC^{2}

AC^{2} +a^{2} +a^{2} =2a^{2}

AC=\sqrt{2a}     Equation 1

Again by Pythagoras' theorem in second half

AD^{2} =AC^{2} +CD^{2}

AD^{2} =(\sqrt{Aa}) ^{2} +(a)^{2}

AD^{2} +2a^{2} +a^{2} =3a^{2}

AD=\sqrt{3a}      Equation 2

From relation 1 and 2 we get,

\sqrt{3a} =4r

a=\frac{4}{\sqrt{3} } r

so the relation is \sqrt{3a}=4r

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