relationship between cp and cv ____❤❤⬅⬅⬅
AlizaQureshi:
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Consider 1 mole of an ideal gas at constant volume to increase the temperature dt,then
⟹dQ=CvdT
From 1st Law of Thermodynamics
dQ=du+PdV
At constant volume dv=0,then
dQ=du
du=CvdT →1
If the temperature is increased by same amount of heat supplied to gas at constant pressure i.e, dQ=CpdT.
⟹du+PdV= CpdT
From 1 we have CvdT + PdV=CpdT→2
we know that PdV=RdT
By substituting value of P in 2
⟹CvdT+RdT=CpdT
Cv+R=Cp
Cp-Cv=R
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