Replacement of diazonium ground by halogen atom can be done by the reaction
(a) Ullmann reaction
(c) Sandmeyer's reaction
(b) Fittig reaction
(d) Friedel Craft reaction
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Replacement by a hydroxyl group The phenol formed may react with the diazonium salt and hence the reaction is carried in the presence of an acid which suppresses this further reaction. A Sandmeyer-type hydroxylation is also possible using Cu2O and Cu2+ in water.
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