requirements for a system to be in thermodynamics equilibrium
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For a completely isolated system, S is maximum at thermodynamic equilibrium. For a system with controlled constant temperature and volume, A is minimum at thermodynamic equilibrium. For a system with controlled constant temperature and pressure, G is minimum at thermodynamic equilibrium.
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For a thermodynamic system to be in equilibrium, all intensive (temperature, pressure) and extensive thermodynamic properties (U, G, A, H, S, etc) must be constants. Hence, the total change in any of those properties (dℑ ) must be zero at equilibrium.
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