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In simple cubic unit cell, two atoms touch along the edge of the unit cell.
For simple cubic cell, the relationship between the edge length a and the radius r is a=2r.
The volume of the unit cell V=a³=(2r)³=8r³
Each simple cubic cell contains eight atoms present at eight corners. Each atom contributes one eight to the unit cell. Hence, number of atoms present in one unit cell= 8× 1/8 = 1.
The volume occupied by one atom in unit cell = 4/3 πr².
packing efficiency=
Volume occupied by one atom
————————————————— × 100
Volume of unit cell.
packing efficiency = 4/3 πr²/ 8 r³ × 100.
= 52.4%.
Hence, the percentage efficiency of packing in case of simple cubic cell is 52.4 %.
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