Role of cryolite in the extraction of aluminium from pure alumina
Answers
◼Aluminium is a metal and almost non electrolyte with high boiling and melting point around 2050 degress so a large amount of heat energy is required to attain aluminium while to attain such high temperature much of fuel was getting wasted .
◼The pure aluminium that will be obtained may get volatize and may get wasted.
So fused cryolite is added because:-
▶It lowers the fusion point if mixture to 950 from 2050 degrees.
▶It enchances the mobility the fused mixture .It dissolves the aluminium oxide.
▶It enchances the conductivity of the mixture since , pure alumina is a non conductor of electricity.
a) Role of cryolite
It lowers the melting points of the mixture .
It makes alumina a good conduction of electricity
(b) When nickel is heated with carbon monoxide it forms a volatile complex nickel tetracarbonyl which on further heating at higher temperature decomposes to give pure nickle.