Role of molten cryolute in extraction of aluminium
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Molten cryolite is used as a solvent for aluminium oxide (Al2O3) in the Hall–Héroult process, used in the refining of aluminium. It decreases the melting point of molten (liquid state) aluminium oxide from 2000–2500 °C to 900–1000 °C, thus making the extraction of aluminium more economical
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Instead, it is dissolved in molten cryolite – an aluminium compound with a lower melting point than aluminium oxide. The use of molten cryolite as a solvent reduces some of the energy costs involved in extracting aluminium by allowing the ions in aluminium oxide to move freely at a lower temperature.
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