S i f 6 - 2 is known where as sicl6-2 is not
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Because SiF-6 is stable and the other is an unstable compound.........
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❤⭐MAIN REASONS:- ⭐❤
- six large chloride ions cannot be accomodated around due to of its size.
- Interaction between lone pair of chloride ion and is not very strong.
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