screening constant Sigma and Zeff for 3D electron in MN respectively
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Explanation:
Step 1: Write the electron configuration of the atom in the following form:
(1s) (2s, 2p) (3s, 3p) (3d) (4s, 4p) (4d) (4f) (5s, 5p) . . .
Step 2: Identify the electron of interest, and ignore all electrons in higher groups (to the right in the list from Step 1). These do not shield electrons in lower groups
Step 3: Slater's Rules is now broken into two cases:
the shielding experienced by an s- or p- electron,
electrons within same group shield 0.35, except the 1s which shield 0.30
electrons within the n-1 group shield 0.85
electrons within the n-2 or lower groups shield 1.00
the shielding experienced by nd or nf valence electrons
electrons within same group shield 0.35
electrons within the lower groups shield 1.00
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