show the structural formula of= ketone by butane
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In chemistry, a ketone (alkanone) /ˈkiːtoʊn/ is an organic compound with the structure RC(=O)R', where R and R' can be a variety of carbon-containing substituents. Ketones and aldehydes are simple compounds that contain a carbonyl group (a carbon-oxygen double bond). They are considered "simple" because they do not have reactive groups like −OH or −Cl attached directly to the carbon atom in the carbonyl group, as in carboxylic acidscontaining −COOH.[1] Many ketones are known and many are of great importance in industry and in biology. Examples include many sugars (ketoses) and the industrial solvent acetone, which is the smallest ketone.Aldehydes and ketones are both carbonyl compounds. They are organic compounds in which the carbonyl carbon is connected to C or H atoms on either side. An aldehyde has one or both vacancies of the carbonyl carbon satisfied by a H atom, while a ketone has both its vacancies satisfied by carbon.Since aldehydes and ketones contain a polar carbonyl group, the partially positive carbon atom can act as an electrophile. Strong and weak nucleophiles are able to attack this carbonyl carbon, resulting in a net addition to the molecule.
Nucleophilic additionEdit
With cyanide, nucleophilic addition occur to give a hydroxynitrile:
RR'C=O + CN- + H+ → RR'COHCN
e.g. propanone → 2-hydroxymethylpropanonitrile
Reactions with the carbonyl oxygenEdit
The partially negative oxygen can act as a nucleophile, or be attacked by electrophiles.
OxidationEdit
Using a strong oxidizing agent such as the Tollens' Reagent (Ag2O in aqueous ammonia) acidified dichromate, Benedict's/Fehling's reagent (essentially alkaline Cu+2); aldehydes but not ketones may be oxidized into carboxylic acids. This is one way to test for the presence of an aldehyde in a sample compound: an aldehyde will become a carboxylic acid when reacted with Tollens' reagent, but a ketone will not react. when aldehydes react with fehling solution a red precipitate is obtained (due to formation of Cu2O) .
Nucleophilic additionEdit
With cyanide, nucleophilic addition occur to give a hydroxynitrile:
RR'C=O + CN- + H+ → RR'COHCN
e.g. propanone → 2-hydroxymethylpropanonitrile
Reactions with the carbonyl oxygenEdit
The partially negative oxygen can act as a nucleophile, or be attacked by electrophiles.
OxidationEdit
Using a strong oxidizing agent such as the Tollens' Reagent (Ag2O in aqueous ammonia) acidified dichromate, Benedict's/Fehling's reagent (essentially alkaline Cu+2); aldehydes but not ketones may be oxidized into carboxylic acids. This is one way to test for the presence of an aldehyde in a sample compound: an aldehyde will become a carboxylic acid when reacted with Tollens' reagent, but a ketone will not react. when aldehydes react with fehling solution a red precipitate is obtained (due to formation of Cu2O) .
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