Smith rearrangement carboxylic acid and their deriatives reats with hydozoic acid and further hydrolysis will provide primary amine
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It is named after Karl Friedrich Schmidt (1887–1971), who first reported it in 1924 by successfully converting benzophenone and hydrazoic acid to benzanilide. ... The reaction is effective with carboxylic acids to give amines (above), and with ketones to give amides (below)
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The Schmidt reactions refer to the acid-catalyzed reactions of hydrazoic acid with electrophiles, such as carbonyl compounds, tertiary alcohols and alkenes. These substrates undergo rearrangement and extrusion of nitrogen to furnish amines, nitriles, amides or imines
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