SO2 acts as a reducing as well as an oxidizing agent whereas SO3 acts only as an oxidizing agent. Why ???
Answers
This is because in SO2 , Sulphur has vacant d orbital but this is not so in SO3 . Hence it acts only as an oxidizer . If SO3 acted as a reducing agent , it would achieve an oxidation higher than what is already has in SO3 .
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In SO2 sulphur having oxidation state +4 so it can lose its two more electrons to attain+6 oxidation state. Therefore it can lose and gain electron therefore it acts as oxidising as well as reducing agent.
SO2 can act as both oxidising as well as reducing agent because it has (+4) oxidation state, which is exactly between its highest O.S. (+6) and lowest O.S. (+2).
SO2 can act as both oxidising as well as reducing agent because it has (+4) oxidation state, which is exactly between its highest O.S. (+6) and lowest O.S. (+2).Hence, it can change its oxidation no. either from (+4) to (+2) [Reduction] or from (+4) to (+6) [Oxidation]. Whereas SO3 is already in it's highest O.S.and hence can only reduce its oxidation number.
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