Solution ofethyl alcohol in water shows positive deviation from raoults law.explain why
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In pure ethyle glycol ,molecules are hydrogen bonded.Onadding water ,its molecules get in between the host molecules&breaks some hydrogen bonds between them.Due to weekning in intractions,the solution the solution shows positive deviation.
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Any ideal solution obeys Roult's law.In ideal solution the solute-solute,solute-solvent and solvent- solvent Interactions are same. For this reason ΔH(mix) and ΔV(mix) is zero.
Solution of ethyl alcohol in water shows positive deviation from raoults law because here the solute-solute,solute-solvent and solvent- solvent Interactions are not same.
Here P>pixi+pyxy.
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