Solutions which will show negitive deviation for Raoult's law is
1) CHCl3 + CH3COCH3
2) CH3COCH3 + CS2
3) CH3OH + H2O
4) C2H5OH + CH3COCH3
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When acetone and chloroform are mixed together a hydrogen bond is formed between them which increases inter molecular attraction between them. Hence, it shows the negative deviation.
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