Chemistry, asked by anaskhan7055, 11 months ago

some note of hunds rule

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Answered by tarunshamra771999
2

Answer: Hund's Rule. Hund's rule: every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied, and all electrons in singly occupied orbitals have the same spin.

Explanation: The Aufbau section discussed how that electrons fill the lowest energy orbitals first, and then move up to higher energy orbitals only after the lower energy orbitals are full. However, there a problem with this rule. Certainly, 1s orbitals should be filled before 2s orbitals, because the 1s orbitals have a lower value of n, and thus a lower energy. What about the three different 2p orbitals? In what order should they be filled? The answer to this question involves Hund's rule.

Hund's rule states that:

Every orbital in a sublevel is singly occupied before any orbital is doubly occupied.

All of the electrons in singly occupied orbitals have the same spin (to maximize total spin).

When assigning electrons to orbitals, an electron first seeks to fill all the orbitals with similar energy (also referred to as degenerate orbitals) before pairing with another electron in a half-filled orbital. Atoms at ground states tend to have as many unpaired electrons as possible. In visualizing this process, consider how electrons exhibit the same behavior as the same poles on a magnet would if they came into contact; as the negatively charged electrons fill orbitals, they first try to get as far as possible from each other before having to pair up.

Answered by Anonymous
0

Hund's rule of maximum multiplicity is a rule based on observation of atomic spectra, which is used to predict the ground state of an atom or molecule with one or more open electronic shells.

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