species of hydrogen
Answers
In view of the widespread use in biochemistry of labelling with hydrogen isotopes, recent IUPAC recommendations [2] for unambiguous naming of these isotopes may interest biochernists. There is often little harm in current practice of using the name 'proton' both for 1H+ and for H+ in its natural abundance of isotopes, but there are contexts in discussing isotope effects where distinction is necessary. The names listed in Table 1 allow the ambiguities to be avoided. Thus the general terms allow description of experiments on reaction mechanism, e.g. where hydronation is specifically with 2H+ or with 3H+, where the term 'protonation' would be misleading. The use of the recommendations may be illustrated by the following example: 'The observation of a protium/deuterium kinetic isotope effect may be interpreted in terms of the extent of hydron transfer in the transition state'.
Table 1. Names for hydrogen species
General 1H 2H 3H
Atom (H) hydrogen protium deuterium tritium
Cation (H+) hydron proton deuteron triton
Anion (H-) hydride protide deuteride tritide
Group (-H) hydro protio deuterio tritio
Transfer of cation to substrate hydronation protonation deuteronation tritonation
Replacement of hydrogen by a specific isotope protiation deuteriation
(or deuteration) tritiation
Answer:
Protium (atmic no1)
Deutrium(2)
Tritium(3)
Explanation: