state and explain Fajan's rule?
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Fajans' rule states that a compound with low positive charge, large cation and small anion has ionic bond where as a compound with high positive charge, small cation and large anion are covalently bonded. For high charge, small cation will have more polarizing power.
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» For a given cation, covalent character Increases with increase in size of the anion
» For a given anion, covalent character increases with a decrease in the size of the cation
» Covalent character Increseas with increasing charge either on cation or an anion
» Covalent character is higher for compounds with cations with pseudo noble gas electronic configuration
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